Over maturing organic hydrocarbon source rocks generates H2
Hydrocarbon source rocks, deposited in the subsurface, generate oil and/or gas when being exposed to high temperatures and pressure (thermal maturation process).
Excessive temperatures (more then ~400dC) over a prolonged period results in the generation of H2 as part of the fusing of aromatic kerogens. Above ~650dC, H2 is the only product generated from thermal maturation process of organic material.
This process is independent of the type of organic hydrocarbon source rocks.
In petroleum basins, this process could lead to significant volumes of H2 being generated.